8.2 Group I properties

1. Alkali metals

Group I elements are called alkali metals, which include lithium, sodium and potassium, and other metals in group I.

Alkali metals are metals, and they will show most typical properties of metals. Beside these, alkali metals show some special physical properties:

  • soft
  • low melting points (decreasing mp down the group)
  • low density (increasing density down the group)

metaldensity
g/cm3
melting point
boiling point
hardness
lithium0.531811342fairly soft
sodium0.9798883soft
potassium0.86*63760very soft
* the density of rubidium and caesium are 1.53 and 1.88, respectively

2. Chemical properties of alkali metals

Alkali metals are the most reactive metals because only one electron will be lost for them to form a stable electronic structure. All of them can react with water to produce an alkaline solution and hydrogen gas.

alkali metal + water → hydroxide + hydrogen
2M + 2H2O → 2MOH + H2
M can represent any alkali metals, such as
2Na + 2H2O → 2NaOH + H2

Down the group, the reactivity increases due to easier to lose electron at outermost shell.

metalgas productionheat produced by reactionproduction of alkaline solutionproduction of flame
lithiumfizzes slowly, a few bubblesmoves slowly on the surface, does not meltmetal disappears slowly, solution turn purpleno flame
sodiumfizzes strongly, many bubblesmelts into a ball on surface and moves aboutmetal disappears quickly, solution turns purpleno flame unless held in place
potassiumfizzes violently, very many bubblesmelts and moves very quickly on surfacedisappears very quickly, solution turns purplehydrogen ignites, a lilac flame produced

Due to increasing reactivity down the group, rubidium and caesium will be more reactive when they react with water.


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