11.1 Formulae, functional groups and terminology

Organic compounds can be classified into different groups to be learnt, which is called homologous series. The features of homologous series are listed as follows:

  • having the same functional group
  • having the same general formula
  • differing from one member to the next by 
  • a –CH2– unit
  • displaying a trend in physical properties
  • sharing similar chemical properties due to same functional group

The common homologous series we should understand are:

  • alkanes
  • alkenes
  • alcohols
  • carboxylic acids

The following homologous series should understand due to the products from reactions involving series above.

  • halogenoalkanes (especially, monohalogenoalkanes)
  • esters

2. Formulae

FormulaMeaningExample: C5H10
General formulaCnH2n
Empirical formulathe simplest whole number ratio of the different atoms or ions in a compoundCH2
Molecular formulathe number and type of different atoms in one moleculeC5H10
Structural formulaan unambiguous description of the way the atoms in a molecule are arrangedCH2=CHCH2CH2CH3
Displayed formulato show all the atoms and all the bonds

3. Other terms

Saturation:
Saturated: all carbon-carbons are single bonds
Unsaturated: one or more carbon-carbon bonds are not single bonds

Hydrocarbons: contain hydrogen and carbon only

Structural isomers: compounds with the same molecular formula, but different structural formulae.


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